Enhanced visible and near infrared emissions via Ce(3+) to Ln(3+) energy transfer in Ln(3+)-doped CeF3 nanocrystals (Ln = Nd and Sm).

We report the enhancement of both visible and near infrared (NIR) emissions from Nd(3+) ions via Ce(3+) sensitization in colloidal nanocrystals for the first time. This is achieved in citrate capped Nd(3+)-doped CeF3 nanocrystals under ultraviolet (UV) irradiation (λex = 282 nm). The lasing transition ((4)F3/2 → (4)I11/2) at 1064 nm from Nd(3+)-doped CeF3 nanocrystals has much higher emission intensity via Ce(3+) ion sensitization compared to the direct excitation of Nd(3+) ions. The nanocrystals were prepared using a simple microwave irradiation route. Moreover, the study has been extended to Sm(3+)-doped CeF3 nanocrystals which show strong characteristic emissions of Sm(3+) ions via energy transfer from Ce(3+) ions. The energy transfer mechanism from Ce(3+) to Nd(3+) and Sm(3+) ions is proposed.